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Reactions between terrigenous sediments, marine-biogenic substances and seawater modulate multiple biogeochemical cycles, but the dynamics and factors governing these reactions are poorly constrained. Deltaic mobile muds are a major sedimentary facies along river-dominated ocean margins through which most terrigenous sediment transits and mixes with marine-biogenic matter, representing efficient and globally significant batch reactors. Here, we present a process-based model that combines equilibrium aqueous chemistry with kinetic concepts from sediment biogeochemistry and mineral sciences to explore the solution-mediated interplay of organic and inorganic matter alteration in episodically reworked deltaic muds. The model reproduces observed diagenetic conditions and product suites over the seasonal timescales relevant to deltaic systems and indicates a systematic and dynamic coupling between the sedimentary cycles of H⁺, C, P, Fe, S, Si, Mg, K, and Ca. We used the model in combination with published field observations and concepts of authigenic mineral occurrences to develop a generalized explanatory framework for silicate weathering fluxes and diagenetic reaction balances in marine sediments. Diagenetic silicate weathering is represented by a continuum of reaction balances with acid (reverse) and alkaline (forward) endmembers that is moderated by sediment sources, which determine the sediment’s weatheringpotential, and depositional environments, which govern theexpressionof this potential. Reverse weathering dominates in seasonally reworked, low-latitude deltaic muds, where green clays form rapidly from lateritic river sediments and biogenic silica under suboxic conditions. High mineral precipitation rates and protracted sediment remobilization drive large solute fluxes from/to these sediments. Net forward silicate weathering becomes more likely under steady, sustained anoxic conditions, particularly in volcanically-influenced settings and at minimal pre-weathering of sediment sources. These results further our understanding of the role silicate weathering and marine sediments play in global biogeochemistry and Earth system evolution, and can aid targeted ‘enhanced weathering’ strategies to environmental governance. 

Abstract. The Oligocene (33.9–23.03 Ma) had warm climates with flattened meridional temperature gradients, while Antarctica retained a significant cryosphere. These may pose imperfect analogues to distant future climate states with unipolar icehouse conditions. Although local and regional climate and environmental reconstructions of Oligocene conditions are available, the community lacks synthesis of regional reconstructions. To provide a comprehensive overview of marine and terrestrial climate and environmental conditions in the Oligocene, and a reconstruction of trends through time, we review marine and terrestrial proxy records and compare these to numerical climate model simulations of the Oligocene. Results, based on the present relatively sparse data, suggest temperatures around the Equator that are similar to modern temperatures. Sea surface temperatures (SSTs) show patterns similar to land temperatures, with warm conditions at mid- and high latitudes (∼60–90°), especially in the Southern Hemisphere (SH). Vegetation-based precipitation reconstructions of the Oligocene suggest regionally drier conditions compared to modern times around the Equator. When compared to proxy data, climate model simulations overestimate Oligocene precipitation in most areas, particularly the tropics. Temperatures around the mid- to high latitudes are generally underestimated in models compared to proxy data and tend to overestimate the warming in the tropics. In line with previous proxy-to-model comparisons, we find that models underestimate polar amplification and overestimate the Equator-to-pole temperature gradient suggested from the available proxy data. This further stresses the urgency of solving this widely recorded problem for past warm climates, such as the Oligocene. 

Abstract. Climate variability is typically amplified towards polar regions. The underlying causes, notably albedo and humidity changes, are challenging to accurately quantify with observations or models, thus hampering projections of future polar amplification. Polar amplification reconstructions from the ice-free early Eocene (∼56–48 Ma) can exclude ice albedo effects, but the required tropical temperature records for resolving timescales shorter than multi-million years are lacking. Here, we reconstruct early Eocene tropical sea surface temperature variability by presenting an up to ∼4 kyr resolution biomarker-based temperature record from Ocean Drilling Program (ODP) Site 959, located in the tropical Atlantic Ocean. This record shows warming across multiple orbitally paced carbon cycle perturbations, coeval with high-latitude-derived deep-ocean bottom waters, showing that these events represent transient global warming events (hyperthermals). This implies that orbital forcing caused global temperature variability through carbon cycle feedbacks. Importantly, deep-ocean temperature variability was amplified by a factor of 1.7–2.3 compared to the tropical surface ocean, corroborating available long-term estimates. This implies that fast atmospheric feedback processes controlled meridional temperature gradients on multi-million year, as well as orbital, timescales during the early Eocene. Our combined records have several other implications. First, our amplification factor is somewhat larger than the same metric in fully coupled simulations of the early Eocene (1.1–1.3), suggesting that models slightly underestimate the non-ice-related – notably hydrological – feedbacks that cause polar amplification of climate change. Second, even outside the hyperthermals, we find synchronous eccentricity-forced temperature variability in the tropics and deep ocean that represent global mean sea surface temperature variability of up to 0.7 °C, which requires significant variability in atmospheric pCO2. We hypothesize that the responsible carbon cycle feedbacks that are independent of ice, snow, and frost-related processes might play an important role in Phanerozoic orbital-scale climate variability throughout geological time, including Pleistocene glacial–interglacial climate variability. 

Abstract. Eocene transient global warming events (hyperthermals) can provide insight into a future warmer world. While much research has focused on the Paleocene–Eocene Thermal Maximum (PETM), hyperthermals of a smaller magnitude can be used to characterize climatic responses over different magnitudes of forcing. This study identifies two events, namely the Eocene Thermal Maximum 2 (ETM2 and H2), in shallow marine sediments of the Eocene-aged Salisbury Embayment of Maryland, based on magnetostratigraphy, calcareous nannofossil, and dinocyst biostratigraphy, as well as the recognition of negative stable carbon isotope excursions (CIEs) in biogenic calcite. We assess local environmental change in the Salisbury Embayment, utilizing clay mineralogy, marine palynology, δ18O of biogenic calcite, and biomarker paleothermometry (TEX86). Paleotemperature proxies show broad agreement between surface water and bottom water temperature changes. However, the timing of the warming does not correspond to the CIE of the ETM2 as expected from other records, and the highest values are observed during H2, suggesting factors in addition to pCO2 forcing have influenced temperature changes in the region. The ETM2 interval exhibits a shift in clay mineralogy from smectite-dominated facies to illite-rich facies, suggesting hydroclimatic changes but with a rather dampened weathering response relative to that of the PETM in the same region. Organic walled dinoflagellate cyst assemblages show large fluctuations throughout the studied section, none of which seem systematically related to CIE warming. These observations are contrary to the typical tight correspondence between climate change and assemblages across the PETM, regionally and globally, and ETM2 in the Arctic Ocean. The data do indicate very warm and (seasonally) stratified conditions, likely salinity-driven, across H2. The absence of evidence for strong perturbations in local hydrology and nutrient supply during ETM2 and H2, compared to the PETM, is consistent with the less extreme forcing and the warmer pre-event baseline, as well as the non-linear response in hydroclimates to greenhouse forcing. 

Abstract. The early and late Eocene have both been the subject of many modelling studies, but few have focused on the middle Eocene. The latter still holds many challenges for climate modellers but is also key to understanding the events leading towards the conditions needed for Antarctic glaciation at the Eocene–Oligocene transition. Here, we present the results of CMIP5-like coupled climate simulations using the Community Earth System Model (CESM) version 1. Using a new detailed 38 Ma geography reconstruction and higher model resolution compared to most previous modelling studies and sufficiently long equilibration times, these simulations will help to further understand the middle to late Eocene climate. At realistic levels of atmospheric greenhouse gases, the model is able to show overall good agreement with proxy records and capture the important aspects of a warm greenhouse climate during the Eocene. With a quadrupling of pre-industrial concentrations of both CO2 and CH4 (i.e. 1120 ppm and ∼2700 ppb, respectively, or 4 × PIC; pre-industrial carbon), sea surface temperatures correspond well to the available late middle Eocene (42–38 Ma; ∼ Bartonian) proxies. Being generally cooler, the simulated climate under 2 × PIC forcing is a good analogue for that of the late Eocene (38–34 Ma; ∼ Priabonian). Terrestrial temperature proxies, although their geographical coverage is sparse, also indicate that the results presented here are in agreement with the available information. Our simulated middle to late Eocene climate has a reduced Equator-to-pole temperature gradient and a more symmetric meridional heat distribution compared to the pre-industrial reference. The collective effects of geography, vegetation, and ice account for a global average 5–7 ∘C difference between pre-industrial and 38 Ma Eocene boundary conditions, with important contributions from cloud and water vapour feedbacks. This helps to explain Eocene warmth in general, without the need for greenhouse gas levels much higher than indicated by proxy estimates (i.e. ∼500–1200 ppm CO2) or low-latitude regions becoming unreasonably warm. High-latitude warmth supports the idea of mostly ice-free polar regions, even at 2 × PIC, with Antarctica experiencing particularly warm summers. An overall wet climate is seen in the simulated Eocene climate, which has a strongly monsoonal character. Equilibrium climate sensitivity is reduced (0.62 ∘C W−1 m2; 3.21 ∘C warming between 38 Ma 2 × PIC and 4 × PIC) compared to that of the present-day climate (0.80 ∘C W−1 m2; 3.17 ∘C per CO2 doubling). While the actual warming is similar, we see mainly a higher radiative forcing from the second PIC doubling. A more detailed analysis of energy fluxes shows that the regional radiative balance is mainly responsible for sustaining a low meridional temperature gradient in the Eocene climate, as well as the polar amplification seen towards even warmer conditions. These model results may be useful to reconsider the drivers of Eocene warmth and the Eocene–Oligocene transition (EOT) but can also be a base for more detailed comparisons to future proxy estimates. 

Abstract. Cenozoic stable carbon (δ13C) and oxygen (δ18O)isotope ratios of deep-sea foraminiferal calcite co-vary with the 405 kyreccentricity cycle, suggesting a link between orbital forcing, the climatesystem, and the carbon cycle. Variations in δ18O are partlyforced by ice-volume changes that have mostly occurred since the Oligocene.The cyclic δ13C–δ18O co-variation is found inboth ice-free and glaciated climate states, however. Consequently, thereshould be a mechanism that forces the δ13C cyclesindependently of ice dynamics. In search of this mechanism, we simulate theresponse of several key components of the carbon cycle to orbital forcing inthe Long-term Ocean-atmosphere-Sediment CArbon cycle Reservoir model(LOSCAR). We force the model by changing the burial of organic carbon in theocean with various astronomical solutions and noise and study the responseof the main carbon cycle tracers. Consistent with previous work, thesimulations reveal that low-frequency oscillations in the forcing arepreferentially amplified relative to higher frequencies. However, whileoceanic δ13C mainly varies with a 405 kyr period in themodel, the dynamics of dissolved inorganic carbon in the oceans and ofatmospheric CO2 are dominated by the 2.4 Myr cycle of eccentricity.This implies that the total ocean and atmosphere carbon inventory is stronglyinfluenced by carbon cycle variability that exceeds the timescale of the405 kyr period (such as silicate weathering). To test the applicability ofthe model results, we assemble a long (∼22 Myr) δ13C andδ18O composite record spanning the Eocene to Miocene(34–12 Ma) and perform spectral analysis to assess the presence of the2.4 Myr cycle. We find that, while the 2.4 Myr cycle appears to beovershadowed by long-term changes in the composite record, it is present asan amplitude modulator of the 405 and 100 kyr eccentricity cycles.